Change in groundwater chemistry as a consequence of suppression of floods: the case of the Rhine floodplain

Spatio-temporal variations of nitrogen, phosphorus and base cation concentrations in groundwater were related to the drastic change in hydrological conditions of the Rhine alluvial floodplain (Eastern France), which has been disconnected from the river by canalisation. The Groundwater chemistry was studied in two alluvial forests with contrasting hydrological conditions: one in a sector unflooded for 30 years, the second one in a sector still subject to flooding. Nutrient concentrations were measured at two levels, in the root zone (1.5 m depth) and in the gravel below the root layer (4.5 m depth). In the unflooded sector, the average nitrate concentration was significantly lower in the shallow groundwater (2.06 mg l−1 NO3−) than in the deeper layer (5.84 mg l−1NO3−). In contrast, in the flooded sector the nitrate concentrations in the shallow groundwater (5.02 mg l−1 NO3−) were not significantly different from those in the deep groundwater (3.98 mg l−1 NO3−). The concentration of phosphate was similar in shallow and deep groundwater in the unflooded sector (46 and 35 μg l−1, respectively) but significantly lower in the deep groundwater of the flooded sector (47 μg l−1), than in the shallow groundwater (58 μg l−1). The major elements (cations: Ca2+, Mg2+, Na+ and associated anions: HCO3−, SO4−2, Cl−) concentrations were significantly higher in the groundwaters than in the surface water. The results are discussed in terms of changes that accompanied suppression of floods, and processes that take place during the transfer of nutrients through the groundwater–soil–plant compartments. The reduction of groundwater fluctuations in the unflooded sector modified the transfer of nitrate by reducing the resolubilisation of locally produced nitrate, and/or denitrification. The transfer of phosphate was affected to a lesser extent, because of precipitation and adsorption. Base cation concentrations reflect exchange between groundwater and the calcareous gravel

Temporal variability of nitrate transport through hydrological response during flood events within a large agricultural catchment in south-west France

The temporal variability of nitrate transport was monitored continuously in a large agricultural catchment, the 1110 km2 Save catchment in south-west France, from January 2007 to June 2009. The overall aim was to analyse the temporal transport of nitrate through hydrological response during flood events in the catchment. Nitrate loads and hysteresis were also analysed and the relationships between nitrate and hydro-climatological variables within flood events were determined. During the study period, 19 flood events were analysed using extensive datasets obtained by manual and automatic sampling. ThemaximumNO3 − concentration during flood varied from 8.2 mg l−1 to 41.1 mg l−1 with flood discharge from 6.75 m3 s−1 to 112.60 m3 s−1. The annual NO3 − loads in 2007 and 2008 amounted to 2514 t and 3047 t, respectively, with average specific yield of 2.5 tkm−12 yr−1. The temporal transport of nitrate loads during different seasonal flood events varied from 12 t to 909 t. Nitrate transport during flood events amounted to 1600 t (64% of annual load; 16% of annual duration) in 2007 and 1872 t (62% of annual load; 20% of annual duration) in 2008. The level of peak discharge during flood events did not control peak nitrate concentrations, since similar nitrate peaks were produced by different peak discharges. Statistically strong correlations were found between nitrate transport and total precipitation, flood duration, peak discharge and total water yield. These four variables may be the main factors controlling nitrate export from the Save catchment. The relationship between nitrate and discharge (hysteresis patterns) investigated through flood events in this study was mainly dominated by anticlockwise behaviour

Predicting soil water and mineral nitrogen contents with the STICS model for estimating nitrate leaching under agricultural fields

The performance of the STICS soil-crop model for the dynamic prediction of soil water content (SWC) and soil mineral nitrogen (SMN) in the root zone (120 cm) of seven agricultural fields was evaluated using field measurements in a coarse-grained alluvial aquifer of the Garonne River floodplain (southwestern France) from 2005 to 2007. The STICS model was used to simulate drainage and nitrate concentration in drainage water in all the agricultural fields of the study area, in order to quantify and assess the temporal and spatial variability of nitrate leaching into groundwater. Simulations of SWC and SMN in the seven monitored fields were found to be satisfactory as indicated by root mean square error (RMSE) and model efficiency being 6.8 and 0.84% for SWC and 22.8 and 0.92% for SMN, respectively. On average, SWC was slightly overestimated by a mean difference of 10 mm (3%) and there was almost no bias in SMN estimations (<0.5%). These satisfactory results demonstrate the potential for using the STICS model to accurately simulate nitrate leaching. Across the study area, simulated drainage and nitrate concentration were extremely variable from one field to another. For some fields, simulated mean annual nitrate concentration in drainage water exceeded 300 mg NO3 − L−1 and predicted nitrate leaching was close to 100 kg N ha−1, while other fields had very low nitrate losses. About 15% of the farmers’ fields were responsible for 60–70% of nitrate leaching. The SMN in late autumn, before winter drainage, was found the main determining factor explaining this variability. This situation may be attributed to unsatisfactory cumulative nitrogen management over the medium term. Ineffective nitrogen management was found to be more detrimental than a single annual incident of overfertilization, particularly in situations of deep soils and in cases of low or highly variable drainage between years

Nitrate elimination by denitrification in hardwood forest soils of the Upper Rhine floodplain – correlation with redox potential and organic matter

Denitrification in floodplains is a major issue for river- and groundwater quality. In the Upper Rhine valley, floodplain forests are about to be restored to serve as flood retention areas (polders). Besides flood attenuation in downstream areas, improvement of water quality became recently a major goal for polder construction. Redox potential monitoring was suggested as a means to support assessment of nitrogen elimination in future floodplains by denitrification during controlled flooding. To elucidate the relationship between redox potential and denitrification, experiments with floodplain soils and in situ measurements were done. Floodplain soil of two depth profiles from a hardwood forest of the Upper Rhine valley was incubated anaerobically with continuous nitrate supply. Reduction of nitrate was followed and compared with redox potential and organic matter content. The redox potential under denitrifying conditions ranged from 10 to 300 mV. Redox potential values decreased with increasing nitrate reduction rates and increasing organic matter content. Furthermore, a narrow correlation between organicmatter and nitrate reduction was observed. Experiments were intended to help interpreting redox potentials generated under in situ conditions as exemplified by in situ observations for the year 1999. Results obtained by experiments and in situ observations showed that monitoring of redox potential could support management of the flooding regime to optimize nitrogen retention by denitrification in future flood retention areas

Assessment of hydrology, sediment and particulate organic carbon yield in a large agricultural catchment using the SWAT model

The Soil and Water Assessment Tool (SWAT, 2005) was used to simulate discharge and sediment transport at daily time steps within the intensively farmed Save catchment in south-west France (1110 km2). The SWAT model was applied to evaluate catchment hydrology and sediment and associated particulate organic carbon yield using historical flow and meteorological data for a 10-years (January 1999–March 2009). Daily data on sediment (27 months, January 2007–March 2009) and particular organic carbon (15 months, January 2008–March 2009) were used to calibrate the model. Data on management practices (crop rotation, planting date, fertiliser quantity and irrigation) were included in the model during the simulation period of 10 years. Simulated daily discharge, sediment and particulate carbon values matched the observed values satisfactorily. The model predicted that mean annual catchment precipitation for the total study period (726 mm) was partitioned into evapotranspiration (78.3%), percolation/groundwater recharge (14.1%) and abstraction losses (0.5%), yielding 7.1% surface runoff. Simulated mean total water yield for the whole simulation period amounted to 138 mm, comparable to the observed value of 136 mm. Simulated annual sediment yield ranged from 4.3 t km−2 y−1 to 110 t km−2 y−1 (annual mean of 48 t km−2 y−1). Annual yield of particulate organic carbon ranged from 0.1 t km−2 y−1 to 2.8 t km−2 y−1 (annual mean of 1.2 t km−2 y−1). Thus, the highest annual sediment and particulate carbon yield represented 25 times the minimum annual yield. However, the highest annual water yield represented five times the minimum (222 mm and 51 mm, respectively). An empirical correlation between annual water yield and annual sediment and organic carbon yield was developed for this agricultural catchment. Potential source areas of erosion were also identified with the model. The range of the annual contributing erosive zones varied spatially from 0.1 to 6 t ha−1 according to the slope and agricultural practices at the catchment scale

Impact of river management history on the community structure, species composition and nutrient status in the Rhine alluvial hardwood forest

The present-day Rhine alluvial hardwood forest (Querco-Ulmetum minoris, Issler 24) in the upper Rhine valley (France/Germany) is comprised of three vegetation units, one still flooded by calm waters (F) and the two others unflooded, one for 30 years (UF30) (after the river canalisation) and the other for about 130 years (UF130) (after river straightening and embankment work in the middle nineteenth century). In the three stands, species composition, structure and diversity of vegetation and nutrient content of mature leaf, leaf litter and soil have been studied. Fungi (Macromycetae) were only studied in two stands (F and UF130). The intensity of nutrient recycling was exemplified by comparing the chemical composition of rainwater, flood, throughfall, mature leaf, leaf litter, soil and groundwater in two of these stands (F and UF30). The elimination of floods has caused a change in floristic composition, tree density and plant diversity. Tree density was higher in the two unflooded stands and was related to a large increase in sapling (< 6 cm dbh) density more than to a change of stem (> 6 cm dbh) density. Sapling density increased 2 times and three times in the UF30 and the UF130 respectively, whereas the stem density increased only 12% in the first stand and decreased 29% in the second one. The saprophytic macromycete communities have been supplemented with mycorrhizal species

Changes in foliar nutrient content and resorption in Fraxinus excelsior L., Ulmus minor Mill. and Clematis vitalba L. after prevention of floods

This paper focuses on the impact of flood on tree mineral nutrition through measurement of resorption (i.e. transfer of nutrients from leaves to perennial organs). Nutrient (N, P, K, Mg, Ca) concentrations in leaves of three representative species, Fraxinus excelsior L., Ulmus minor Mill. and Clematis vitalba L. were measured before and after abscission on flooded and unflooded hardwood forests of the upper Rhine plain. The nutrient concentrations in the soils, which were measured in the top layer of the study sites, were higher in the flooded sites for P but slightly lower for N and K, and identical at both types of site for Ca and Mg. The summer foliage concentrations were higher for N and P in the flooded areas, and probably related to the flooding process, which contributes to regular nutrient inputs in the flooded forest, causes high fluctuations of water level and increases bioavailability of certain nutrients. Resorption occurred for all nutrients in the three species, and was higher for N, P and K (40-70 %) than for Ca and Mg (0-45 %), but not significantly different at the two sites. This paper stresses the variability of the test species response (nutrient content and resorption) to the soil and flood water nutrient sources, and tries to specify parameters which control resorption, i.e. soil fertility, tree species or flood stress. © 1999 Inra/Éditions scientifiques et médicales Elsevier SAS

Impact of river management history on the community structure, species composition and nutrient status in the Rhine alluvial hardwood forest

The present-day Rhine alluvial hardwood forest (Querco-Ulmetum minoris, Issler 24) in the upper Rhine valley (France/Germany) is comprised of three vegetation units, one still flooded by calm waters (F) and the two others unflooded, one for 30 years (UF30) (after the river canalisation) and the other for about 130 years (UF130) (after river straightening and embankment work in the middle nineteenth century). In the three stands, species composition, structure and diversity of vegetation and nutrient content of mature leaf, leaf litter and soil have been studied. Fungi (Macromycetae) were only studied in two stands (F and UF130). The intensity of nutrient recycling was exemplified by comparing the chemical composition of rainwater, flood, throughfall, mature leaf, leaf litter, soil and groundwater in two of these stands (F and UF30). The elimination of floods has caused a change in floristic composition, tree density and plant diversity. Tree density was higher in the two unflooded stands and was related to a large increase in sapling (< 6 cm dbh) density more than to a change of stem (> 6 cm dbh) density. Sapling density increased 2 times and three times in the UF30 and the UF130 respectively, whereas the stem density increased only 12% in the first stand and decreased 29% in the second one. The saprophytic macromycete communities have been supplemented with mycorrhizal species

On modeling chronic detachment of periphyton in artificial rough, open channel flow

Periphyton communities, which are native to river beds, serve as a functional indicator of river health but remain one of the least-studied communities despite the significant increase in the examination of aquatic microbial communities in recent years. In this study, we tested the relevance of three formulations of the chronic detachment term in a simple model for the biomass dynamics of periphyton. Numerical simulations of the periphyton biomass dynamics were performed by using three different descriptors for the flow conditions: the discharge Q, the friction velocity u⁄, and the roughness Reynolds number k+ = u⁄ks/m (where m is water kinetic viscosity and ks is the Nikuradse equivalent sand roughness). Comparisons of numerical simulation results with experimental data from literature revealed chronic detachment to be better simulated by taking the roughness Reynolds number as the external variable of detachment. These results support the idea that transport phenomena that occur in the nearbed layer, e.g. chronic detachment of periphyton matter or vertical transport of nutrients and pollutants in submerged aquatic canopies, are not related to a single turbulence descriptor such as the friction velocity u⁄. Its description requires at least two descriptors, here the friction velocity u⁄ and the Nikuradse equivalent sand roughness ks, which depend on the initial form and dimensions of the colonized substratum, and its changes owing to the thickness, resistance, and composition of the epilithic matter

The influence of nitrate leaching through unsaturated soil on groundwater pollution in an agricultural area of the Basque country: a case study

The average nitrate concentration in the groundwater of the Vitoria-Gasteiz (Basque Country) quaternary aquifer rose from 50 mg NO3−/l during 1986 to over 200 mg/l in 1995, which represents an increase of some 20 mg NO3−/l per year. From 1995 to 2002, the nitrate concentration of the groundwater slightly decreased. Nitrategroundwaterpollution during the period 1986–1993 was the result of the abusive use of fertilizers and of the modification in the recharge patterns of the aquifer from surface water sources. From 1993 onwards, apart from a possible rationalization in fertilizer use, the change in the origin of water for irrigation and wetland restoration (water is taken now from artificial pools outside the quaternary aquifer) must be explained in order to account for the observed decrease in nitrate concentration in the groundwater. The water of the aquifer and of the unsaturated zone were studied in two experimental plots (one of them cultivated and the other uncultivated) for 18 months (January 1993–June 1994), during the period of maximum contamination, to evaluate the effect of fertilizers on soil water and on the water in the saturated zone. The soil water was sampled using soil lysimeters at various depths. The volumetric water content of the soil was measured at the same depths using time domain reflectrometry (TDR) probes. Samples of groundwater were taken from a network of wells on the aquifer scale, two located close to the two experimental plots. The temporal evolution of nitrate concentrations in soil solutions depends on the addition of fertilizers and on soilnitrateleaching by rain. During episodes of intense rain (>50 mm in a day), the groundwater deposits are recharged with water coming from the leaching of interstitial soil solutions, causing an increase in the groundwaternitrate concentrations. The mass of nitrate leached from the cultivated zone is five times higher than that of the nitrate leached from the uncultivated zone (1147 kg NO3−/ha in the cultivated sector as against 211 kg NO3−/ha in the uncultivated sector), although part of the nitrate leached into the soil had been previously deposited by the rise of the water table. If we consider that the level of groundwater input is similar in both plots, we may conclude that 964 kg NO3−/ha circulated towards the groundwater in the cultivated zone during the period under study, representing 87% of the nitrate applied to the soil in the form of fertilizer during that period